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Chemistry Lessons Review Links

Molecular Formula from Epirical Formula and Mass

Problem: A compound has an empirical formula of ClCH2 and a molecular weight of 98.96 g/mol. What is its molecular formula?

Strategy:

  1. Find the mass of the empirical unit.
    Mass of empirical unit = mass Cl + mass C + 2(mass H)

    Mass of empirical unit = 35.45 + 12.00 + 2(1.008) = 49.47 g/mol
     
  2. Figure out how many empirical units are in a molecular unit.
     
    # of empirical units = (mass of molecular unit/ mass of empirical unit)
    (98.96 g/mol) / (49.47 g/mol) = 2.000 empirical units per molecular unit

     
  3. Write the molecular formula.

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